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1

[Advances in Physical Organic Chemistry] Advances in Physical Organic Chemistry Volume 40 Volume 40 || Mechanisms of hydrolysis and rearrangements of epoxides

Whalen, Dale L.

Year:

2005

Language:

english

File:

PDF, 1004 KB

english, 2005

2

Pentacyclo[4.4.0.02,5.03,8.04,7]decane and pentacyclo[4.3.0.02,5.03,8.04,7]nonane

William G. Dauben, Dale L. Whalen

Journal:

Tetrahedron Letters

Year:

1966

Language:

english

File:

PDF, 319 KB

english, 1966

3

Embedded behavioral health providers: An assessment with the Army National Guard.

Russell, Dale W., Whalen, Ronald J., Riviere, Lyndon A., Clarke-Walper, Kristina, Bliese, Paul D., Keller, Darc D., Pangelian, Susan I., Thomas, Jeffrey L.

Journal:

Psychological Services

Year:

2014

Language:

english

File:

PDF, 100 KB

english, 2014

4

The BB/Wor Rat and the Balance Hypothesis of Autoimmunity

John P. Mordes, Rita Bortell, John Doukas, Mark Rigby, Barbara Whalen, Danny Zipris, Dale L. Greiner, Aldo A. Rossini

Journal:

Diabetes/Metabolism Research and Reviews

Year:

1996

Language:

english

File:

PDF, 746 KB

english, 1996

5

ChemInform Abstract: Acid-Catalyzed Phenylcyclohexene Oxide Hydrolysis: Role of para-Phenyl Substituent on syn:anti Hydration Ratio.

Lanxuan Doan, Kevin Bradley, Sonya Gerdes, Dale L. Whalen

Journal:

Year:

2000

File:

PDF, 27 KB

2000

6

ChemInform Abstract: New Insights on the Mechanisms of the pH-Independent Reactions of Benzo[a]pyrene 7,8-Diol 9,10-Epoxides.

Lanxuan Doan, Bin Lin, Haruhiko Yagi, Donald M. Jerina, Dale L. Whalen

Journal:

Year:

2001

File:

PDF, 27 KB

2001

7

Mechanism of the “spontaneous” reaction of p-methoxystyrene oxide in aqueous solution

Victoria C. Ukachukwu, Dale L. Whalen

Journal:

Tetrahedron Letters

Year:

1988

Language:

english

File:

PDF, 258 KB

english, 1988

8

Acetolysis of oxirylcarbinyl chloride (epichlorohydrin) and oxirylcarbinyl p-bromobenzenesulfonate

Journal:

Tetrahedron Letters

Year:

1978

Language:

english

File:

PDF, 274 KB

english, 1978

9

Aryl epoxide–halohydrin transformations: stereochemistry of reactions of aryl epoxides with lithium halide–acetic acid reagent

Jeanne-Marie Bartas-Yacoubou, Nkabuije Maduike, Sampson Kyere, Lanxuan Doan, Dale L. Whalen

Journal:

Tetrahedron Letters

Year:

2002

Language:

english

File:

PDF, 63 KB

english, 2002

10

Mercury-induced autoimmunity in Brown Norway rats: kinetics of changes in RT6+ T lymphocytes correlated with IgG isotypes of circulating autoantibodies to laminin 1

Linda L Kosuda, Barbara Whalen, Dale L Greiner, Pierluigi E Bigazzi

Journal:

Year:

1998

Language:

english

File:

PDF, 180 KB

english, 1998

11

Hydrogen bonding incis-2,3-epoxycyclooctanol

H. L. Carrell, Dale L. Whalen, Jenny P. Glusker

Journal:

Structural Chemistry

Year:

1997

Language:

english

File:

PDF, 399 KB

english, 1997

12

Stretch-Activated Receptors Mediate Cardiac Memory

MOHAMMAD KOOSHKABADI, PATRICK WHALEN, DALE YOO, JONATHAN LANGBERG

Journal:

Pacing and Clinical Electrophysiology

Year:

2009

Language:

english

File:

PDF, 299 KB

english, 2009

13

Evidence for reversible formation of an intermediate in the "spontaneous" hydrolysis reaction of p-methoxystyrene oxide

Ukachukwu, Victoria C., Blumenstein, Jeffrey J., Whalen, Dale L.

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 277 KB

english, 1986

14

Changes of mechanisms and product distributions in the hydrolysis of benzo[a]pyrene-7,8-diol 9,10,-epoxide metabolites induced by changes in pH

Whalen, Dale L., Montemarano, Jean A., Thakker, Dhiren R., Yagi, Haruhiko, Jerina, Donald M.

Journal:

Journal of the American Chemical Society

Year:

1977

Language:

english

File:

PDF, 378 KB

english, 1977

15

Separation of underivatized gangliosides by ion exchange high performance liquid chromatography

Marge M. Whalen, Gaynor C. Wild, W. Dale Spall, Robert J. Sebring

Journal:

Year:

1986

Language:

english

File:

PDF, 447 KB

english, 1986

16

Adoptive Transfer of Autoimmune Diabetes Mellitus to Athymic Rats: Synergy of CD4+ and CD8+ T Cells and Prevention by RT6+ T Cells

Barbara J. Whalen, Dale L. Greiner, John P. Mordes, Aldo A. Rossini

Journal:

Journal of Autoimmunity

Year:

1994

File:

PDF, 405 KB

1994

17

Type 1 cytokines polarize thymocytes during T cell development in adult thymus organ cultures

Barbara J Whalen, Jan Marounek, John P Mordes, Aldo A Rossini, Dale L Greiner

Journal:

Journal of Autoimmunity

Year:

2003

Language:

english

File:

PDF, 602 KB

english, 2003

18

Transition-State Effects in Acid-Catalyzed Aryl Epoxide Hydrolyses

Sampson, Kyere, Paik, Augustine, Duvall, Bridget, Whalen, Dale L.

Journal:

Journal of Organic Chemistry

Year:

2004

Language:

english

File:

PDF, 165 KB

english, 2004

19

Specific effects of chloride ion on epoxide hydrolysis. The pH-dependence of the rates and mechanisms for the hydrolysis of indene oxide

Whalen, Dale L., Ross, Angela M.

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 378 KB

english, 1976

20

Structural effects on the rates of formation and the stability of enols of cyclic benzyl ketones

Eldin, Sherif, Pollack, Ralph M., Whalen, Dale L.

Journal:

Journal of the American Chemical Society

Year:

1991

Language:

english

File:

PDF, 878 KB

english, 1991

21

Rearrangement of Protonated Propene Oxide to Protonated Propanal

Coxon, James M., Maclagan, Robert G. A. R., Rauk, Arvi, Thorpe, Aaron J., Whalen, Dale

Journal:

Journal of the American Chemical Society

Year:

1997

Language:

english

File:

PDF, 181 KB

english, 1997

22

Effects of para-substituents on the mechanisms of solvolysis of styrene oxides

Blumenstein, Jeffrey J., Ukachukwu, Victoria C., Mohan, Ram S., Whalen, Dale L.

Journal:

Journal of Organic Chemistry

Year:

1993

Language:

english

File:

PDF, 1.24 MB

english, 1993

23

The acidity of benzyl ketones in aqueous solution. Evaluation of the intrinsic acidifying effect of a phenyl group

Ross, Angela M., Whalen, Dale L., Eldin, Sherif., Pollack, Ralph M.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 273 KB

english, 1988

24

Substituent effects on rates and product distributions in the hydrolysis reactions of naphthalene tetrahydro epoxides. Models for tetrahydro epoxides of polycyclic aromatic hydrocarbons

Gillilan, Richard E., Pohl, Terese M., Whalen, Dale L.

Journal:

Journal of the American Chemical Society

Year:

1982

Language:

english

File:

PDF, 295 KB

english, 1982

25

Spontaneous Hydrolysis Reactions of cis - and trans -β-Methyl-4-methoxystyrene Oxides (Anethole Oxides): Buildup of trans -Anethole Oxide as an Intermediate in the Spontaneous Reaction of cis -Anethole Oxide

Mohan, Ram S., Gavardinas, Kostas, Kyere, Sampson, Whalen, Dale L.

Journal:

Journal of Organic Chemistry

Year:

2000

Language:

english

File:

PDF, 129 KB

english, 2000

26

Acid-catalyzed hydrolysis of cis- and trans-anethole oxides: discrete carbocation intermediates and syn/anti hydration ratios

Mohan, Ram S., Whalen, Dale L.

Journal:

Journal of Organic Chemistry

Year:

1993

Language:

english

File:

PDF, 932 KB

english, 1993

27

Stereochemistry of the Spontaneous, Acid-Catalyzed and Base-Catalyzed Hydrolyses of Styrene Oxide

Lin, Bin, Whalen, Dale L.

Journal:

Journal of Organic Chemistry

Year:

1994

Language:

english

File:

PDF, 421 KB

english, 1994

28

Chloride Ion Catalyzed Conformational Inversion of Carbocation Intermediates in the Hydrolysis of a Benzo[ a ]pyrene 7,8-Diol 9,10-Epoxide

Doan, Lanxuan, Yagi, Haruhiko, Jerina, Donald M., Whalen, Dale L.

Journal:

Journal of the American Chemical Society

Year:

2002

Language:

english

File:

PDF, 168 KB

english, 2002

29

Transition State Effects in the Acid-Catalyzed Hydrolysis of 5-Methoxyacenaphthylene 1,2-Oxide: Implications for the Mechanism of Acid-Catalyzed Hydrolysis of Cyclopenta[ cd ]pyrene 3,4-Oxide

Zhao, Chumang, Whalen, Dale L.

Journal:

Chemical Research in Toxicology

Year:

2006

Language:

english

File:

PDF, 104 KB

english, 2006

30

pH dependence of the mechanism of hydrolysis of benzo[a]pyrene-cis-7,8-diol 9,10-epoxide catalyzed by DNA, poly(G), and poly(A)

Islam, Nafisa B., Whalen, Dale L., Yagi, H., Jerina, Donald M.

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 523 KB

english, 1987

31

Rearrangement of a non-arene oxide via an NIH shift related mechanism

Whalen, Dale L., Ross, Angela M.

Journal:

Journal of the American Chemical Society

Year:

1974

Language:

english

File:

PDF, 274 KB

english, 1974

32

Change of Rate Limiting Step in General Acid-Catalyzed Benzo[ a ]pyrene Diol Epoxide Hydrolysis

Lin, Bin, Islam, Nafisa, Friedman, Steve, Yagi, H., Jerina, Donald M., Whalen, Dale L.

Journal:

Journal of the American Chemical Society

Year:

1998

Language:

english

File:

PDF, 138 KB

english, 1998

33

New Insights on the Mechanisms of the pH-Independent Reactions of Benzo[ a ]pyrene 7,8-Diol 9,10-Epoxides

Doan, Lanxuan, Lin, Bin, Yagi, Haruhiko, Jerina, Donald M., Whalen, Dale L.

Journal:

Journal of the American Chemical Society

Year:

2001

Language:

english

File:

PDF, 86 KB

english, 2001

34

Solvolysis of (4-Nitrophenoxy)ethylene Oxides

Shipley, David S., Ross, Angela M., Mohan, Ram S., Whalen, Dale L., Sayer, Jane M., Serve, Paul M., Jerina, Donald M.

Journal:

Journal of Organic Chemistry

Year:

1994

Language:

english

File:

PDF, 948 KB

english, 1994

35

Vinyl epoxide hydrolysis reactions

Ross, Angela M., Pohl, Terese M., Piazza, Kathryn, Thomas, Michael, Fox, Bonnie, Whalen, Dale L.

Journal:

Journal of the American Chemical Society

Year:

1982

Language:

english

File:

PDF, 1.04 MB

english, 1982

36

Trapping of a carbocationic intermediate in the spontaneous hydrolysis reaction of 7.beta.,8.alpha.-dihydroxy-9.beta.,10.beta.-epoxy-7,8,9,10-tetrahydrobenzo[a]pyrene: mechanism of the spontaneous and general acid catalyzed hydrolysis reactions of bay-region benzo[a]pyrene 7,8-diol 9,10-epoxides

Islam, Nafisa B., Gupta, Satish C., Yagi, H., Jerina, Donald M., Whalen, Dale L.

Journal:

Journal of the American Chemical Society

Year:

1990

Language:

english

File:

PDF, 1.03 MB

english, 1990

37

Structural effects on charge delocalization in benzylic anions

Eldin, Sherif, Whalen, Dale L., Pollack, Ralph M.

Journal:

Journal of Organic Chemistry

Year:

1993

Language:

english

File:

PDF, 812 KB

english, 1993

38

Epoxycarbinyl solvolyses. Lack of significant participation by epoxide oxygen in the hydrolysis of acyclic secondary epoxycarbinyl substrates

Whalen, Dale L., Brown, Steven, Ross, Angela M., Russell, Helen Miller

Journal:

Journal of Organic Chemistry

Year:

1978

Language:

english

File:

PDF, 668 KB

english, 1978

39

Nonclassical homoallylic cations and homoallylic ring expansions

Gasic, Miroslav., Whalen, Dale., Johnson, Brian., Winstein, Saul.

Journal:

Journal of the American Chemical Society

Year:

1967

Language:

english

File:

PDF, 391 KB

english, 1967

40

pH dependence of the mechanism of hydrolysis of benzo[a]pyrene-cis-7,8-diol 9,10-epoxide catalyzed by DNA, poly(G), and poly(A) [Erratum to document cited in CA106(15):114999v]

Islam, Nafisa B., Whalen, Dale L., Yagi, H., Jerina, Donald M.

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 134 KB

english, 1988

41

Halide Effects in the Hydrolysis Reactions of (±)-7β,8α-Dihydroxy-9α,10α-epoxy-7,8,9,10-tetrahydrobenzo- [ a ]pyrene

Lin, Bin, Doan, Lanxuan, Yagi, Haruhiko, Jerina, Donald M., Whalen, Dale L.

Journal:

Chemical Research in Toxicology

Year:

1998

Language:

english

File:

PDF, 198 KB

english, 1998

42

Mechanism of the acid- and general-base-catalyzed conjugation of 3-cyclopentenone and 3-cyclohexenone; electrostatic effects in the conjugation of .beta.,.gamma.-unsaturated ketones

Whalen, Dale L., Weimaster, John F., Ross, Angela M., Radhe, Richard

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 753 KB

english, 1976

43

Solvolysis of Pentacyclo[4.4.0.0 2,5 .0 3,8 .0 4,7 ]dec-9-yl Methanesulfonate (1,1'-Bishomocubyl Mesylate) and Pentacyclo[4.3.0.0 2,5 .0 3,8 .0 4,7 ]nonane-9-carbinyl p-Toluenesulfonate (Homocubylcarbinyl Tosylate) 1

Dauben, William G., Whalen, Dale L.

Journal:

Journal of the American Chemical Society

Year:

1966

Language:

english

File:

PDF, 244 KB

english, 1966

44

Bifunctional catalysis in the nucleotide-catalyzed hydrolysis of (.+-.)-7.beta.,8.alpha.-dihydroxy-9.alpha.,10.alpha.-epoxy-7,8,9,10-tetrahydrobenzo[a]pyrene

Gupta, Satish C., Islam, Nafisa B., Whalen, Dale L., Yagi, H., Jerina, D. M.

Journal:

Journal of Organic Chemistry

Year:

1987

Language:

english

File:

PDF, 577 KB

english, 1987

45

Molecular Orbital Studies of the Intramolecular Reaction of Protonated cis - and trans -3,4-Epoxypentan-1-ol

Coxon, James M., Morokuma, Keiji, Thorpe, Aaron J., Whalen, Dale

Journal:

Journal of Organic Chemistry

Year:

1998

Language:

english

File:

PDF, 141 KB

english, 1998

46

Synthesis and Hydrolysis of a cis -Chlorohydrin Derived from a Benzo[ a ]pyrene 7,8-Diol 9,10-Epoxide

Doan, Lanxuan, Yagi, Haruhiko, Jerina, Donald M., Whalen, Dale L.

Journal:

Journal of Organic Chemistry

Year:

2004

Language:

english

File:

PDF, 190 KB

english, 2004

47

Synthesis of the tetracyclo[11.1.0.03,5.07.9]tetradecan-11-ols. Possible heptahomotropylium ion precursors

Thies, Richard W., Gasic, M., Whalen, Dale, Grutzner, J. B., Sakai, Mitsuru, Johnson, Brian, Winstein, S.

Journal:

Journal of the American Chemical Society

Year:

1972

Language:

english

File:

PDF, 973 KB

english, 1972

48

Structural effects on the energetics of s-cis and s-trans dienolates

Eldin, Sherif, Whalen, Dale L., Pollack, Ralph M.

Journal:

Journal of Organic Chemistry

Year:

1993

Language:

english

File:

PDF, 623 KB

english, 1993

49

Kinetic studies of the reactions of benzo[a]pyrene-7,8-diol 9,10-epoxides in aqueous solutions of human serum albumin and nonionic micelles

Islam, Nafisa B., Whalen, Dale L., Yagi, H., Jerina, Donald M.

Journal:

Chemical Research in Toxicology

Year:

1988

Language:

english

File:

PDF, 624 KB

english, 1988

50

Acid-Catalyzed Phenylcyclohexene Oxide Hydrolysis: Role of Para-Phenyl Substituent on Syn:Anti Hydration Ratio

Doan, Lanxuan, Bradley, Kevin, Gerdes, Sonya, Whalen, Dale L.

Journal:

Journal of Organic Chemistry

Year:

1999

Language:

english

File:

PDF, 99 KB

english, 1999